Hi floraljo,
Technically, testosterone is slightly higher round about ovulation if you are premenopausal or very early perimenopausal. However the levels don't fluctuate usually by very much - unlike oestrogen.
I do any hormone tests first thing in the morning. When I started on Androfeme I had a test after 6 weeks and then 6 months. Now I need one once a year and otherwise just keep an eye on symptoms.
I use Medichecks and they measure albumin, SHBG, estradiol, total testosterone and free testosterone. You still need to do the calculation for FAI (Total Testosterone รท SHBG - both in same units - x 100).